Haven't seen this mentioned before, so here you go:
Quote:
RONNIE JAMES DIO: More Details Revealed About 'Pick Of Destiny' Soundtrack Appearance - Sep. 25, 2006
Legendary heavy metal vocalist Ronnie James Dio (DIO, RAINBOW, BLACK SABBATH) is featured in the song "Kickapoo", which opens the soundtrack to TENACIOUS D's film "Tenacious D in the Pick of Destiny", due Nov. 14 via Epic. Also making an appearance in the song is Meat Loaf.
[full article on Blabbermouth.net]
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